Step by step process to synch the files from your computer to onedrive. Note: Make sure you already logged into the Outlook web application.
Steps
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1.
Open - Outlook.
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2.
1.Click on App Launcher.
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3.
2.Click on Onedrive.
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4.
3.Click on My files option.
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5.
4.Click on Sync option, and then if any additional prompts are appeared follow those and wait till sync is completed.